酸法地浸采铀中信息参数的判断及其应用     

雷奇峰  唐文杰 《华东地质学院学报》2009,32(4):378-380

介绍了酸法地浸采铀工艺信息技术的显示,在长期生产和科研实践的基础上,总结归纳了酸法地浸采铀工艺的基本信息技术,以及如何利用这些信息对地浸开采实现有效的判断和调控,这些内容是地浸工作者必备和需要掌握的重要开采技术和手段。  相似文献   

Cu2+和Cd2+在蒙脱石-胡敏酸复合体上的吸附及其竞争   总被引：1，自引：0，他引：1  

李福春  何为红  滕飞  李学林  代静玉 《岩石矿物学杂志》2009,28(3):285-291

土壤和水体中的腐殖酸常常与粘土矿物紧密结合成为特殊的复合体.这种粘土矿物-腐殖酸复合体对重金属的吸附作用既有别于粘土矿物,更有别于腐殖酸.以蒙脱石和胡敏酸分别作为粘土矿物和腐殖酸的代表,通过一系列实验研究了Cu2+、Cd2+在单一体系和共存体系条件下在蒙脱石-胡敏酸复合体上的吸附作用,同时探讨了二者的竞争特点.实验结果表明,在单一体系条件下,蒙脱石-胡敏酸复合体对Cu2+的吸附量始终明显大于Cd2+,且二者的吸附量均随其初始浓度的增大而呈线性增大;而在Cu2+和Cd2+共存体系条件下,Cu2+的吸附量始终略大于Cd2+的吸附量,即复合体对Cu2+的吸附有较好的选择性.在吸附过程中,复合体中的蒙脱石与Cd2+和Cu2+的阳离子交换作用处于主导地位.无论是在单一体系还是在共存体系中,Cd2+优先替换电价相同而半径略大的Ca2+,而Cu2+则优先替换半径相近、电价低的Na+.因此,Cd2+的存在使Cu2+在复合体上的吸附量明显地减小,而Cu2+的存在对Cd2+的吸附几乎没有影响.这些实验结果将有助于深入探讨重金属离子在土壤、水体等环境中的迁移-固定行为.  相似文献   

降水化学特性的一种分类分析方法   总被引：30，自引：1，他引：29  

程新金  黄美元 《气候与环境研究》1998,3(1):82-88

在分析比较不同地区降水化学特性时,如果列出各种离子的具体数值,既显得繁琐又不容易得出结论。现提出一种简便方法,即先概括出几种最重要的降水化学特性,分别以字母代表,再把这些特性分成几个等级以数字表示,就能很直观方便地比较这些地区的降水化学特性。还利用权威观测资料,以上述方法具体比较了世界主要酸雨地区的降水化学特性。  相似文献   

Electron accepting capacity of dissolved organic matter as determined by reaction with metallic zinc   总被引：2，自引：0，他引：2  

Christian Blodau  Markus Bauer  Simona Regenspurg  Donald Macalady 《Chemical Geology》2009,260(3-4):186-195

Information about the chemical electron accepting capacity (EAC) of dissolved organic matter (DOM) is scarce owing to a lack of applicable methods. We quantified the electron transfer from metallic Zn to natural DOM in batch experiments at DOC concentrations of 10–100 mg-C L^− 1 and related it to spectroscopic information obtained from UV-, synchronous fluorescence, and FTIR- spectroscopy. The electron donating capacity of DOM and pre-reduced DOM was investigated using Fe(CN)₆³⁻ as electron acceptor. Presence of DOM resulted in release of dissolved Zn, consumption of protons, and slower release of hydrogen compared to reaction of metallic Zn with water at pH 6.5. Comparison with reaction stoichiometry confirmed that DOM accepted electrons from metallic Zn. The release of dissolved Zn was dependent on pH, DOC concentration, ionic strength, and organic matter properties. The reaction appeared to be completed within about 24 h and was characterized by pseudo first order kinetics with rate constants of 0.5 to 0.8 h^− 1. EAC per mass unit of carbon ranged from 0.22 mmol g^− 1 C to 12.6 mmol g^− 1 C. Depending on the DOM, a calculated 28–127% of the electrons transferred from metallic Zn to DOM could be subsequently donated to Fe(CN)₆³⁻. EAC decreased with DOC concentration, and increased with aromaticity, carboxyl, and phenolic content of the DOM. The results indicate that an operationally defined EAC of natural DOM can be quantified by reaction with metallic Zn and that DOM properties control the electron transfer. Shortcomings of the method are the coagulation and precipitation of DOM during the experiment and the production of hydrogen and dissolved Zn by reaction of metallic Zn with water, which may influence the determined EAC.  相似文献   

不同类型氢氧化镁阻燃剂填充聚丙烯（PP）复合材料力学性能研究   总被引：1，自引：1，他引：0       下载免费PDF全文

姬连敏  李丽娟  孙秋菊  陈大福  聂峰  曾忠民  宋富根  刘志启 《盐湖研究》2009,17(4):46-52

研究了普通氢氧化镁(MH)、六角片状MH和硬脂酸改性MH分别填充聚丙烯(PP)复合材料的性能。用FTIR、SEM和TG对上述3种类型MH及其复合材料的结构和形貌进行了分析。试验结果表明:相比普通MH,六角片状MH和硬脂酸改性后的MH有效降低了表面极性,大大降低了对复合材料的力学性能的影响,显著提高了复合材料的热稳定性;4%SA改性MH比6%SA改性MH填充PP,界面相容性好,对复合材料力学性能的影响小。硬脂酸湿法表面处理氢氧化镁改性的最佳条件为:硬脂酸用量4%,处理温度85~90℃,处理时间60 min,料浆浓度10%。  相似文献   

降水变化对中国南方强酸雨分布的影响     

谢志清  杜银  曾燕  李亚春  严明良  焦圣明 《地理学报(英文版)》2009,19(4):489-501

Acid rain has been recognized as a serious environmental problem in China since the 1980s, but little is known about the effects of the climatic change in regional precipitation on the temporal and spatial variability of severe acid rain. We present the effects of the re-gional precipitation trend change on the area and intensity of severe acid rain in southern China, and the spatio-temporal distribution characteristics of SO2 and NO2 concentrations are analyzed on the basis of SO2 and NO2 column concentration data. The results are as follows. (1) The emission levels of SO2 and NO2 have reached or passed the precipitation scavenging capacity in parts of southern China owing to the emission totals of SO2 and NO2 increasing from 1993 to 2004. (2) Notable changes in the proportion of cities subject to severe acid rain occurred mainly in the south of the middle-lower reaches of the Yangtze River during 1993-2004. With an abrupt change in 1999, the severe acid rain regions were mainly located in central and western China during 1993-1999 and moved obviously eastward to the south of the lower-middle reaches of the Yangtze River with the proportion of cities subject to se-vere acid rain increasing significantly from 2000 to 2004. (3) The spatial distribution and variation in the seasonal precipitation change rate of more than 10 mm/10a are similar to those of severe acid rain in southern China. An abrupt change in 1999 is seen for winter and summer precipitation, the same as for the proportion of cities subject to severe acid rain in southern China. The significant increase in summer storm precipitation from 1991 to 1999 mitigated the annual precipitation acidity in the south of the Yangtze River and reduced the area of severe acid rainfall. On the other hand, the decrease in storm rainfall in summer ex-panded the area of severe acid rainfall in the south of the Yangtze River in 2000-2006. Therefore, the change in seasonal precipitation is an important factor in the severe acid rain regions moving eastward and expanding in southern China.  相似文献   

双能CT彩色编码技术对痛风患者尿酸盐沉积的应用价值研究          下载免费PDF全文

刘力  金梅  沈剑  林奕军  高振兴  王开乐  陈通 《CT理论与应用研究》2016,25(3):339-348

目的:探讨双源双能量CT(DECT)彩色编码技术对痛风患者不同临床时期尿酸盐结晶与血尿酸的关系,进而评估双能CT成像在痛风筛查中的应用价值。方法:回顾性分析120例高尿酸血症或痛风患者的双能CT成像特点及临床资料,根据临床分期分为两组,男92例,女28例;对照组为非痛风患者30例,男26例,女4例。所有患者手、足均行DECT非增强扫描,薄层重组后将原始数据传至MMWP工作站选择Dual Energy GOUT软件,进行影像后处理,比较痛风患者两期尿酸盐沉积的差异与尿酸值相关性,以及DECT检测尿酸盐沉积部位与临床评估的差异。采用t检验、χ2检验、Fisher精确概率进行统计学分析。结果:三组性别及年龄比较,差异无统计学意义(P_年龄=0.236,P_性别=0.613,P>0.005)。高尿酸组尿酸盐沉积量明显高于尿酸正常组,两组有显著统计学意义(P=0.000,P<0.001);痛风组检出率与对照组相比,差异有显著统计学意义(P=0.000,P<0.001)。结论:DECT成像技术对尿酸盐结晶沉积有很好的显示能力,对高尿酸血症、痛风早期、疑似痛风患者均有较高的检出率,可作为痛风筛选的常规检查项目,具有较高的临床应用价值。   相似文献   

Fe‐modified Clinoptilolite is Effective to Recover Plant Biosurfactants Used for Removing Arsenic From Soil          下载免费PDF全文

Zygmunt Mariusz Gusiatin 《洁净——土壤、空气、水》2015,43(8):1224-1231

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外源脱落酸对低温胁迫下圆柏属植物幼苗生理特性的影响     

杨志娟  陈银萍  李冬花  张正庆  郝海艳  张风霞  苏向楠 《冰川冻土》2015,37(6):1642-1649

以3 a生圆柏和祁连圆柏幼苗为材料, 采用不同浓度脱落酸(ABA)预处理两种圆柏属幼苗, 测定-4℃低温胁迫处理第9 d叶片相对含水量(RWC)、相对电导率(REC)、丙二醛(MDA)、可溶性糖(SS)、可溶性蛋白(SP)、脯氨酸(Pro)和类胡萝卜素(Car)含量及超氧化物歧化酶(SOD)、过氧化物酶(POD)、过氧化氢酶(CAT)、抗坏血酸氧化酶(APX)和谷胱甘肽还原酶(GR)活性, 分析外源ABA对低温胁迫下圆柏属植物叶片膜脂过氧化和渗透调节物质的影响, 为培育较多品种的抗冷冻常绿植物提供理论依据. 结果表明: 低温胁迫下, 一定浓度的ABA预处理能有效保护幼苗叶片膜系统的稳定性、增加渗透调节物质含量和提高抗氧化酶活性, 其中30 mg·L^-1ABA预处理对提高圆柏抗寒性效果最好, 40 mg·L^-1ABA预处理对提高祁连圆柏抗寒性效果最好, 且在外源ABA预处理下, 祁连圆柏的抗寒性比圆柏的强. 因此, 施用适合浓度的ABA在提高圆柏属植物抗寒性方面具有较好的应用价值.  相似文献   

基于脂肪酸标记法和碳氮稳定同位素比值法的东海水母常见种的食性分析   总被引：1，自引：0，他引：1  

金鑫  李超伦  刘梦坛 《海洋与湖沼》2012,43(3):486-493

采用脂肪酸标记法和碳氮稳定同位素比值法研究了东海6个水母常见种的食性。结果表明,6种水母的总脂肪酸含量都不高,说明作为饵料,水母不能够给捕食者提供较多的脂类营养物质。蝶水母(Ocyropsis crystallina)、瓜水母(Bero cucumis)和四叶小舌水母(Liriope tetraphylla)的脂肪酸组成较为相近,它们更多地通过捕食食物链获得有机质。同时,这几种小型水母摄食浮游植物(主要是硅藻和甲藻)比其它几种水母多;另外,它们对植食性桡足类也有一定的摄食。4月份墨绿多管水母(Aequorea coerulescens)主要通过腐生食物链获取有机质;另外,其对植食性桡足类也有一定的摄食。双生水母(Diphyidae spp.)参与腐生食物链也较多;另外,20:1+22:1含量较低指示了其对植食性桡足类几乎不摄食。蝶水母、瓜水母、四叶小舌水母和沙海蜇(Nemopilema nomurai)的δ13C更接近于陆源的C4植物的δ13C,说明其受陆源影响较大。δ15N特征结果表明,蝶水母、瓜水母和四叶小舌水母(Liriope tetraphylla)在浮游食物网中均处于较高营养级,沙海蜇虽个体较大,但由于其摄食器官较小,故其与这3种小型水母的营养地位相近。并且相对于其它几种水母,沙海蜇细菌脂肪酸标记更为明显。  相似文献